What information architecture means
Nielsen Norman Group distinguishes two components. The first is identifying and defining the site's content and functionality. The second is the organisation, structure and naming that define how they relate to each other. According to NN/g, information architecture does not appear on screen but informs the interface, and it is documented in spreadsheets and diagrams such as a site map.
Navigation is something else: the interface elements that lead to that information. NN/g lists global navigation, local navigation, breadcrumbs, filters, related links and footers. Both are part of the user experience, which has its own entry in this glossary.
What appears on screen and what lies beneath it.